This issue is mostly related to Microsoft Edge because Edge sometimes automatically saves PDF documents to the default directory.
To do that, run with this:
Step 1:Open theTurn Windows features on or offWindows.
Step 2:Then locateMicrosoft Print to PDFand check it.
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Click OK to save changes.
Step 3:cycle your PC.
Then repeat the same steps and enableMicrosoft Print to PDFagain.

Step 4:ClickOKto save changes.
Now the Print to PDF feature should be working again without any issues.
If the Microsoft Print to PDF not working issue still appears, continue with the following methods.

To do that, you better do the following:
Step 1:Press theWindowskey +Skey and inputprinters.
SelectDevices and Printersfrom the list of results.
Step 2:When theDevices and Printerswindow opens, navigate to thePrinterssection.
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Step 3:LocatePrint to PDF, right-click it and chooseSet as default printer.
If not, try the last method.
When using a printer, it keeps printing pages with the Get/eSCL/ScannerStatus HTTP/1.1 Host: localhost message.
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Here are 8 fixes.
Step 2:ExpandPrint queues.
Right-clickMicrosoft Print to PDF, and go toUpdate driver.
Now, the issue should be fixed.
This post tells you how to fix the another computer is using the printer.
the following status is the usage status of that computer issue in five easy ways.
If you meet the same issue, you’re free to try the methods mentioned above.